(ZrM)-(CuN)-Ni-Al-RE amorphous alloy and manufacturing method and application thereof

The present invention relates to a (ZrM)-(CuN)—Ni—Al-RE amorphous alloy, which containing, by atom percent, 40-65% of Zr, 18-46% of Cu, 2-15% of Ni, 4-15% of Al, 0.1-3% of M, 0.05-3% of N, 0.1-2% of a rare earth element RE, wherein M is Hf and/or Ti; and N is Ag, wherein the amorphous alloy further contains a small amount of Hf, Ti, Ag and Re on the basis of a Zr—Al—Ni—Cu amorphous alloy, to maintain the mechanical properties of the Zr—Al—Ni—Cu amorphous alloy, and has a relatively strong glass froming ability, manufacturability and antimicrobial property.